Well, technically, chitting is not a method of breaking dormancy. Its the seed germination that occurs after dormancy has been broken by some independent means.
For some species just soaking in water can break dormancy better than planting because it washes out dormancy hormones.
Some species wait for a specific number of freeze-thaw cycles or a specific length of time in cold moist soil.
Some species wait on butenolide hormones in smoke.
For some species gibberellic acid is good at breaking dormancy, others are best done by their natural way.
And its hypothetically possible to use cheap and available acid naproxen (or a salt thereof) to prevent a forming seed from building the capacity to be dormant, tho I've never seen this put to the test... its on my list of things to do someday unless I talk about it enough someone beats me to it
Whatever the mechanism, a seed wont germinate until any dormancy it has is at least partly broke. Then if it germinates before planting thats the method of chitting.
Plants are complicated critters